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Factors such as the polarity and geometry of the binding pocket, steric constraints, nucleophilicity and accessibility of the targeted residue, as well as its conformational flexibility, directly modulate k inact and K I , thereby determining both selectivity and efficacy

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[28], such a scenario (a fast reaction following a slow initial step) would change the net stoichiometry (from 1 NO/GSNO to 2 NO/GSNO) but not the order of the reaction

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